Hit 4

FA	RX(1); FLST(1); RX(4)

Reaction (1 of 1)

Reaction ID	3197078
Reactant BRN	5750319
Reactant	4R-(-)-illicinone-A
Product BRN	5750311; 5740842; 5750312; 136380
Product	2S,4R-(-)-illicinone-B; 4-allyl-6-hydroxy-6-(3-methyl-but-2-enyl)-cyclohex-2-enone; 2R,4R-(-)-illicinone-B; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details	4

Reaction Details (1 of 1)

Reaction Classification	Preparation
Yield	0.2 g (BRN=5750311); 90 mg (BRN=5740842); 0.11 g (BRN=5750312); 175 mg (BRN=136380)
Reagent	NaBH4
Solvent	methanol
Time	1 hour(s)
Other Conditions	Ambient temperature
Comment	Further byproducts given
Citation Pointer	5682747; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 32; 1; 1984; 11-22;

Reaction Details (2 of 1)

Reaction Classification	Preparation
Yield	0.11 g (BRN=5750312); 90 mg (BRN=5740842); 175 mg (BRN=136380); 0.2 g (BRN=5750311)
Reagent	NaBH4
Solvent	methanol
Time	1 hour(s)
Other Conditions	Ambient temperature
Comment	Further byproducts given
Citation Pointer	5682747; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 32; 1; 1984; 11-22;

Reaction Details (3 of 1)

Reaction Classification	Preparation
Yield	0.2 g (BRN=5750311); 175 mg (BRN=136380); 90 mg (BRN=5740842); 0.11 g (BRN=5750312)
Reagent	NaBH4
Solvent	methanol
Time	1 hour(s)
Other Conditions	Ambient temperature
Comment	Further byproducts given
Citation Pointer	5682747; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 32; 1; 1984; 11-22;

Reaction Details (4 of 1)

Reaction Classification	Preparation
Yield	0.2 g (BRN=5750311); 175 mg (BRN=136380); 0.11 g (BRN=5750312); 90 mg (BRN=5740842)
Reagent	NaBH4
Solvent	methanol
Time	1 hour(s)
Other Conditions	Ambient temperature
Comment	Further byproducts given
Citation Pointer	5682747; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 32; 1; 1984; 11-22;

Reference (1 of 1)

Citation Number	5682747
Document Type	Journal
Authors	Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.
CODEN	CPBTAL
Journal Title	Chem.Pharm.Bull.
Language Code	EN
(Series) Volume	32
Number	1
Publication Year	1984
Page	11-22